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Since the final application properties of this terpolymer are directly related to its microstructure, it is essential to have a clear understanding of the terpolymerization kinetics. Given that there are three different possibilities for the terminal monomer (on the growing radical), and three options for the added monomer, nine different propagation steps are possible according to the terminal model.
Each of the nine reactions has a rate constant, k ij (radical i adding monomer j ). Six parameters, called monomer reactivity ratios ( r ij ), can be used to describe the potential for homopropagation relative to the potential for cross-propagation.